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Calculating the change in energy

Calculating the change in energy

Let’s consider the reduction in vapor pressure. We can calculate the change in energy that accompanies a change in pressure using the first law of thermodynamics. If we let the symbol U represent the energy in a system and calculate the change in U that occurs when we change the volume, at constant pressure (we assume no heat is added or removed) we can write

Equation 1

dU represents a small change in energy, and dV represents a small change in volume. The relationship between pressure and volume, called the ideal gas law, is

Equation 2

where n is the number of moles of gas, R is a constant, known as the gas constant (8.31 J/mol K) and T is the temperature of the gas in kelvins. We can differentiate the ideal gas law to get dV

Equation 3

Combining this with the first law we get

Equation 4

Now, the energy required to go from the vapor pressure of the pure water in the glass, which we call the saturation vapor pressure or p0, to the vapor pressure of the water in the sponge is

Equation 5

The ratio p /p0 is called the water activity (aw) when we are talking about the water in the sponge or water in foods or other solids or liquids. We call it the relative humidity when we apply it to water in the air and sometimes multiply it by 100 to express it as a percent. The ratio U/n is the energy per mole of water and is called the water potential, with the symbol Ψ. Water potential has units of Joules/mole. With this substitution, we finally arrive at the equation relating the energy of the water in the sponge and its water activity

Equation 6

The equation means that we can express the energy state of the water in a product either as a water potential or as a water activity. Some fields of science use water potential and others use water activity. Some also use freezing point depression or osmolality, but these are all equivalent concepts. There are advantages and disadvantages to each, but the important thing to understand is that all are measures of the energy state of the water and have a strong theoretical basis. Water activity is the measure most widely used in food science and engineering.

What is water activity?

Water activity is directly related to the microbial susceptibility of food products and is correlated with many of the reactions that end shelf life in foods. Learn more about the science …